No...not safely anyway. The magnum chamber is larger in diameter, and the magnum is a tapered case, vs. straight for the LR. There is a possibility of case splitting, allowing hot gas to go where it should not....like your face or body.
Dimensions, LR, vs. Mag
Bullet .223, vs. .224
Neck .225 vs. 240
Base .225 vs. 241.
It's a real shame they didn't make these interchangeable, as the firearm that would shoot both would be much more useful...
Ben